Next Generation Materials for Multi-material LMD: High Conductivity Meets Low Thermal Expansion

Next Generation Materials for Multi-material LMD: High Conductivity Meets Low Thermal Expansion

In today’s manufacturing landscape, the development of novel materials is essential for meeting the growing demand for performance, efficiency, and innovation. New materials are constantly being designed and developed at Makino Additive Manufacturing (AM) to address the limitations of conventional metals and alloys, particularly in processes that involve severe thermal and mechanical loading.

By focusing on improving key properties such as strength, wear resistance, and thermal fatigue, these advanced materials will allow manufacturers to produce components that are more reliable, precise, and cost effective. As a result, novel materials development has now become a key driver of progress across modern manufacturing industries.

One recent development of Makino AM is a novel alloy material, Thexalloy, a high performance material for thermal management purposes.

Thexalloy Key Highlights:

• Up to 250% higher absorptivity than Pure Copper. Enablement of deposition with infrared laser without the use of a substantially higher cost blue/green laser.

• Up to 20% reduction in coefficient of thermal expansion (CTE) than Pure Copper.

• Able to retain up to 70% of the thermal conductivity of Pure Copper.

This material with its unique performance features is well-suited for die and mold applications, where both strength and thermal durability are important.

The Existing Material Challenges

In die and mold applications, material performance can make or break the process. This is why materials testing is so important, especially when evaluating tool steels and copper alloys for improved performance.

Two of the most critical properties to examine are thermal conductivity and coefficient of thermal expansion (CTE). Thermal conductivity determines how efficiently a material can transfer heat, while CTE describes how much it expands and contracts with temperature changes. In die casting, both properties directly affect cycle time, dimensional stability, thermal stress, and ultimately tool life.

Tool steels such as H13 have long been the standard choice because of their excellent strength, hardness, and resistance to wear and thermal fatigue. They are well suited to withstand the harsh mechanical demands of the process. However, one limitation of tool steel is its relatively low thermal conductivity. This means heat is removed more slowly, which can lead to localized heat build-up and longer cooling times.

Copper alloys, on the other hand, are attractive because of their much higher thermal conductivity. They can extract heat much faster, which helps improve temperature control and may reduce cycle times. This makes them especially useful in areas where rapid heat removal is needed.

However, these advantages come with a trade-off. Copper alloys generally have a higher CTE than tool steels, so they expand and contract more under the same thermal conditions. If this difference is not properly managed, it can create thermal mismatch stresses that may cause distortion, cracking, or premature failure.

Also, most industrial metal additive manufacturing systems use near-infrared fibre lasers, with typical wavelengths around 1060–1070 nm. These lasers work very well for many steels, nickel alloys, and titanium alloys because those materials absorb a reasonable amount of laser energy at this wavelength. Copper behaves very differently. At near-infrared wavelengths, copper is highly reflective ( 15% absorptivity), meaning a large portion of the laser energy is reflected away instead of being absorbed by the material.

This poor energy absorption creates inefficient melting. Since copper does not readily absorb infrared laser energy, a much higher laser power is often required just to form a stable melt pool. Even then, the absorbed energy may be inconsistent, especially at the start of processing when the surface is still solid and reflective. This can lead to unstable melting, incomplete bonding between layers, and defects such as lack of fusion.
 

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For copper-based multi-material tooling applications, the challenge is even greater because copper and tool steel respond very differently to the same laser beam. Overcoming this problem requires either improved laser-material coupling, such as through blue or green lasers, or careful alloy and process design to stabilize the melt pool while preserving copper’s valuable thermal properties.
 

Makino’s New Material Development

Thexalloy is an AM powder material that is characterized to deliver excellent heat transfer properties. Through composition engineering, superior strength can be achieved that is particularly ideal for high-temperature and high-stress applications.

The material is designed to overcome low laser absorption; high thermal expansion concerns typically associated with copper-steel multi-material combinations. The tailored alloy composition is a novel material combination with low coefficient of thermal expansion and high thermal conductivity, that results in its unique performance features such as superior softening resistance to maintain structural integrity at high temperatures.

Die and Mold Applications

The die and mold industry is recognized as one of the most demanding manufacturing sectors for a material. The die and surrounding materials are exposed to intense contact pressures, rapid thermal cycling, and harsh operating conditions during repeated casting cycles.

Conventional materials often limit tool life and performance under these conditions, presenting both a significant technical challenge and a valuable opportunity for material innovation.

Advanced materials play a critical role in pushing the capabilities of die and mold toward more demanding industrial applications. Our novel material development in this area focuses on addressing key concerns such as thermal fatigue, wear, heat transfer, strength retention at elevated temperature, and resistance to cracking or distortion.

With our newly developed material alloy system that is specially tailored to offer an improved combination of specific properties, there is a promising capability to achieve longer service life, better casting quality, shorter cycle times, and greater process reliability.
 

 

Die and Mold Applications

Performance Enhancements

A material with excellent thermal conductivity may still perform poorly if its thermal expansion behaviour creates instability during repeated casting cycles. Likewise, a material with strong mechanical performance may still limit process efficiency if it cannot dissipate heat effectively. In the end, the goal is to find the right balance.

The best-performing material is often not simply the strongest or the most conductive, but the one that offers the best overall combination of heat transfer, dimensional compatibility, and durability under real operating conditions.

That is what makes testing thermal conductivity and CTE so important in the development of next-generation materials for die and mold applications.

Our newly developed Thexalloy material offers:
  • Ability to retain high thermal conductivity which gives excellent heat extraction sufficient for rapid cooling, significantly higher than tool steel
  • Lower thermal expansion manages thermal mismatch stresses improving dimensional stability
  • Excellent heat dissipation improves temperature control and helps to reduce cycle times
  • High temperature strength required for extended service life under cyclic heating/cooling
The thermal conductivity and CTE are benchmarked against other Copper alloys and from comparison, the optimal combination of low CTE and high thermal conductivity is best achieved with our Thexalloy material.
 


 

Performance Enhancements